New synthetic method of o,s-thioacetals of formylphosphonates |
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Authors: | Hyeon Kim Taek Young Oh Dong |
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Affiliation: | Department of Chemistry, Korea Advanced Institute of Science and Technology. Seoul 131, Korea |
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Abstract: | The reaction of diethyl [(methylthio or arylthio)methyl]phosphonate with N-chlorosuccinimide (NCS) affords (α-chloromethanephosphonate(5), which can be converted into a variety of O,S-thioacetals of formylphosphonates(2) by reaction with alcohols. |
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