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Straightforward synthesis of phenanthrenes from styrenes and arenes
Authors:Li Hu  He Ke-Han  Liu Jia  Wang Bi-Qin  Zhao Ke-Qing  Hu Ping  Shi Zhang-Jie
Institution:Beijing National Laboratory of Molecular Sciences, College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China.
Abstract:Semi-one-pot synthesis of phenanthrenes from styrenes and arenes was developed through cross-dehydrogenative coupling. A sequence of Heck-type coupling and photo-cyclization were involved and a variety of functionalities were tolerated. This method provides an effective and practical protocol towards the synthesis of substituted phenanthrenes.
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