Straightforward synthesis of phenanthrenes from styrenes and arenes |
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Authors: | Li Hu He Ke-Han Liu Jia Wang Bi-Qin Zhao Ke-Qing Hu Ping Shi Zhang-Jie |
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Institution: | Beijing National Laboratory of Molecular Sciences, College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China. |
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Abstract: | Semi-one-pot synthesis of phenanthrenes from styrenes and arenes was developed through cross-dehydrogenative coupling. A sequence of Heck-type coupling and photo-cyclization were involved and a variety of functionalities were tolerated. This method provides an effective and practical protocol towards the synthesis of substituted phenanthrenes. |
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