| 温和条件原位配体反应合成铁四氮唑配合物及其晶体结构 |
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| 引用本文： | 王榆元,王小峰,聂长明,刘慧君,夏良树,王宏青,肖新荣,王晓晴.温和条件原位配体反应合成铁四氮唑配合物及其晶体结构[J].无机化学学报,2009,25(7):1194-1198. |
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| 作者姓名： | 王榆元 王小峰 聂长明 刘慧君 夏良树 王宏青 肖新荣 王晓晴 |
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| 作者单位： | 1. 南华大学化学化工学院,衡阳,421001
2. 南京农业大学食品工程学院,南京,210093 |
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| 基金项目： | 南华大学科研基金，南华大学博士启动基金 |
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| 摘 要： | 利用2-氰基吡啶与叠氮阴离子，在开放体系、温和条件下发生Demko-Sharpless原位配体反应，合成得到铁四氮唑配合物Fe(2-PTZ)2(H2O)2]。该配合物为单核结构，其晶体属单斜晶系，P21/c空间群。配合物通过分子间的氢键及错位的面对面π-π堆积作用形成三维超分子体系。
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| 关 键 词： | 原位配体反应 四氮唑 铁 晶体结构 |
Crystal Structure of An Ion Coordination Compound with Tetrazolyl Ligand Through In-situ Reaction under Mild Condition |
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| WANG Yu-Yuan,WANG Xiao-Feng,NIE Chang-Ming,LIU Hui-Jun,XIA Liang-Shu,WANG Hong-Qing,XIAO Xin-Rong and WANG Xiao-Qing.Crystal Structure of An Ion Coordination Compound with Tetrazolyl Ligand Through In-situ Reaction under Mild Condition[J].Chinese Journal of Inorganic Chemistry,2009,25(7):1194-1198. |
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| Authors: | WANG Yu-Yuan WANG Xiao-Feng NIE Chang-Ming LIU Hui-Jun XIA Liang-Shu WANG Hong-Qing XIAO Xin-Rong and WANG Xiao-Qing |
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| Institution: | School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001,School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001 and School of Food Engineering, Nanjing Agriculture University, Nanjing 210093 |
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