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Optical spectra of aqueous solutions of glutamine-tryptophan associates
Authors:A. S. Prishchepov  E. K. Pil’ko
Affiliation:(1) Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072 Minsk, Belarus;(2) Belarusian State Institute for Advanced Training of Physicians, Ministry of Public Health of the Republic of Belarus, Minsk
Abstract:
The optical density and luminescence ability of aqueous solutions of glutamine-tryptophan depend on the degree of oxidation of the initial dry substances of dipeptide. Glutamine-tryptophan has a high associating ability, which increases if stored. The general form of the optical absorption and luminescence spectra of the associates differs little from the spectra of monomers. Among the spectral-optical symptoms of association of a substance in a solution for glutamine-tryptophan, we discovered the hypochromism and narrowing of the absorption spectra and shortening of the fluorescence lifetime. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 436–439, July–August, 2000.
Keywords:molecular spectroscopy  aqueous solution  glutamine-tryptophan  associates  dipeptide
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