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“Helter‐Skelter‐Like” Perylene Polyisocyanopeptides |
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| Authors: | Erik Schwartz Vincenzo Palermo Dr. Chris E. Finlayson Dr. Ya‐Shih Huang Matthijs B. J. Otten Andrea Liscio Dr. Sara Trapani Irene González‐Valls Patrick Brocorens Dr. Jeroen J. L. M. Cornelissen Dr. Kalina Peneva Dr. Klaus Müllen Prof. Dr. Frank C. Spano Prof. Dr. Arkady Yartsev Prof. Sebastian Westenhoff Dr. Richard H. Friend Prof. Dr. David Beljonne Dr. Roeland J. M. Nolte Prof. Dr. Paolo Samorì Prof. Dr. Alan E. Rowan Prof. Dr. |
| Affiliation: | 1. Institute for Molecules and Materials, Radboud University Nijmegen, Toernooiveld 1, 6525 Ed Nijmegen (The Netherlands), Fax: (+31)‐24‐3652929;2. Instituto per la Sintesi Organica e la Fotoreattività, (Institution), Consiglio Nazional dlle Ricerche, Via Gobetti 101, 40129 Bologna (Italy);3. Cavendish Laboratory, University of Cambridge, J.?J. Thomson Avenue Cambridge CB3 0HE (UK);4. Université de Mons‐Hainaut, Place du Parc 20, 7000 Mons (Belgium);5. Max‐Planck Institute for Polymer Research, Ackermann 10, 55124 Mainz (Germany);6. Department of Chemistry, Temple University, Beury Hall 201, Philadelphia, PA 19122 (USA);7. Lund University, P.O. Box 124, 22100 Lund (Sweden);8. Nanochemistry Laboratory, ISIS, Université Louis Pasteur and CNRS (UMR 7006), 8 allée Gaspard Monge, 67000 Strasbourg (France) |
| Abstract: | Exciton migration! Spectroscopic analyses and extensive molecular dynamics studies revealed a well‐defined 41 helix in which the perylene molecules (see figure) form four “helter‐skelter‐like” overlapping pathways along which excitons and electrons can rapidly migrate.  |
| Keywords: | electron transport perylene diimides polyisocyanides polymers |