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Spectroscopic Tracking of Molecular Transport Junctions Generated by Using Click Chemistry
Authors:Xiaodong Chen Dr  Adam?B Braunschweig Dr  Michael?J Wiester  Sina Yeganeh  Mark?A Ratner Prof  Chad?A Mirkin Prof
Institution:Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA)
Abstract:Click to fill the gap : The in situ modular fabrication of molecular transport junctions in nanogaps generated by on‐wire lithography is achieved by using click chemistry (see picture). The formation of molecular junctions proceeds in high yields and can be used to test different molecules; the triazole group also maintains conjugation in the molecular wires. Raman spectroscopy is used to characterize the molecular assembly processes.
image

Keywords:click chemistry  fluorene  molecular electronics  nanowires  on‐wire lithography
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