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[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick |
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| Authors: | Tim Ahnfeldt Nathalie Guillou Dr Daniel Gunzelmann Irene Margiolaki Dr Thierry Loiseau Dr Gérard Férey Prof Dr Jürgen Senker Prof Dr Norbert Stock Prof Dr |
| Institution: | 1. Institut für Anorganische Chemie, Christian‐Albrechts‐Universit?t, Max‐Eyth‐Strasse 2, 24118 Kiel (Germany), Fax: (+49)?431‐880‐1775;2. Institute Lavoisier, UMR 8637 CNRS, Université de Versailles‐Saint Quentin, 45 Avenue des états‐Unis, 78035 Versailles (France);3. Anorganische Chemie I, Universit?t Bayreuth, Universit?tsstrasse 30, 95447 Bayreuth (Germany);4. European Synchrotron Radiation Facilities, ID31, Materials Science Group, Inorganic Chemistry I, 6, rue Jules Horowitz, BP 220, 38043 Grenoble (France) |
| Abstract: | Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12‐connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively.  |
| Keywords: | organic– inorganic hybrid composites high‐throughput methods metal– organic frameworks microporous materials solvothermal synthesis |