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Reversible Scrolling of Two‐Dimensional Sheets from the Self‐Assembly of Laterally Grafted Amphiphilic Rods
Authors:Eunji Lee  Jung‐Keun Kim  Myongsoo Lee Prof.
Affiliation:Center for Supramolecular Nanoassembly and Department of Chemistry, Yonsei University, Shinchon 134, Seoul 120‐749 (Korea), Fax: (+82)?2‐393‐6096, http://csna.yonsei.ac.kr
Abstract:Deep‐water scrolls: It is demonstrated that amphiphilic rods containing lateral flexible chains self‐assemble into two‐dimensional sheets in aqueous solution (see picture). Remarkably, the sheets roll up reversibly into tubular scrolls upon heating, as confirmed by cryo‐transmission electron microscopy and fluorescence microscopy.
image

Keywords:amphiphiles  anisotropic sheets  nanotubes  rod–  coil assemblies  self‐assembly
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