Palladium‐Catalyzed Substitution of Allylic Fluorides期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Palladium‐Catalyzed Substitution of Allylic Fluorides

Authors:	Amaruka Hazari Véronique Gouverneur Prof. John M. Brown Dr.

Affiliation:	Chemistry Research Laboratory, Oxford University, 12 Mansfield Rd., Oxford OX1?3TA (UK), Fax: (+44)?1865‐285‐002 http://www.chem.ox.ac.uk/researchguide/vgouverneur.htmlhttp://www.chem.ox.ac.uk/researchguide/jbrown.html

Abstract:	As unusual substrates for the Tsuji–Trost allylation reaction, allylic fluorides are responsive to palladium‐catalyzed substitution. Their activity towards this reaction fits in the series OCO₂Me>OBz? F ?OAc. The classic stereoretention mechanism that involves sequential inversions does not operate in this case. Several distinct cases are considered.

Keywords:	allyl ligands allylation homogeneous catalysis palladium reaction mechanisms