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Self‐Assembly Made Durable: Water‐Repellent Materials Formed by Cross‐Linking Fullerene Derivatives
Authors:Jiaobing Wang Dr  Yanfei Shen Dr  Stefanie Kessel Dr  Paulo Fernandes Dr  Kaname Yoshida Dr  Shiki Yagai Dr  Dirk?G Kurth Prof  Helmuth Möhwald Prof  Takashi Nakanishi Dr
Institution:1. Department of Interfaces, Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Potsdam 14424 (Germany), Fax: (+49)?331‐567‐9202, http://www.nims.go.jp/macromol/nakanishi_eng/index.html;2. Physical Chemistry II, Bayreuth University (Germany);3. Institute for Chemical Research, Kyoto University (Japan);4. PRESTO, Japan Science and Technology Agency (JST, Japan);5. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University (Japan);6. Organic Nanomaterials Center, National Institute for Materials Science (Japan);7. Chemische Technologie der Materialsynthese, Universit?t Würzburg (Germany)
Abstract:Fullerene flakes : A diacetylene‐functionalized fullerene derivative self‐organizes into flakelike microparticles (see picture). Both the diacetylene and C60 moieties can be effectively cross‐linked, which leads to supramolecular materials with remarkable resistivity to solvent, heat, and mechanical stress. Moreover, the surface of the cross‐linked flakelike objects is highly durable and water‐repellent.
image

Keywords:cross‐linking  fullerenes  polydiacetylenes  superhydrophobicity  supramolecular chemistry
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