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Addition of Hydrogen or Ammonia to a Low‐Valent Group 13 Metal Species at 25 °C and 1 Atmosphere |
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| Authors: | Zhongliang Zhu Xinping Wang Dr Yang Peng Hao Lei James?C Fettinger Dr Eric Rivard Dr Philip?P Power Prof |
| Institution: | Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616 (USA), Fax: (+1)?530‐752‐8995 |
| Abstract: | Mild‐mannered : The low‐valent aryl gallium(I) species :GaAr′ (Ar′=2,6‐(2,6‐iPr2C6H3)2C6H3) undergoes addition to H2 or NH3 at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X‐ray crystallography and NMR and IR spectroscopy.  |
| Keywords: | gallium Group 13 elements insertion low‐valent species |