Surface-enhanced oxidation and detection of Sunset Yellow and Tartrazine using multi-walled carbon nanotubes film-modified electrode

The insoluble multi-walled carbon nanotubes (MWNT) was successfully dispersed into water in the presence of hydrophobic surfactant. After that, MWNT film-coated glassy carbon electrode (GCE) was achieved via dip-coating and evaporating water. Owing to huge surface area, high sorption capacity and subtle electronic properties, MWNT film exhibits highly efficient accumulation efficiency as well as considerable surface enhancement effects to Sunset Yellow and Tartrazine. As a result, the oxidation peak currents of Sunset Yellow and Tartrazine remarkably increase at the MWNT film-modified GCE. Based on this, a novel electrochemical method was developed for the simultaneous determination of Sunset Yellow and Tartrazine. The limits of detection are 10.0 ng mL⁻¹ (2.2 × 10⁻⁸ mol L⁻¹) and 0.1 μg mL⁻¹ (1.88 × 10⁻⁷ mol L⁻¹) for Sunset Yellow and Tartrazine. Finally, the proposed method was successfully used to detect Sunset Yellow and Tartrazine in soft drinks.