|
|||||
|
|
Stereoselective synthesis of amides possessing a vinylsilicon functionality via a ruthenium catalyzed silylative coupling reaction |
|
| Authors: | Bogdan Marciniec Dariusz Chadyniak |
| Affiliation: | a Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland b Faculty of Chemistry, Silesian University of Technology, Ks. M. Strzody 9, 44-100 Gliwice, Poland |
| Abstract: | An effective stereoselective synthesis of E-N-2-(silyl)vinylamides via silylative coupling of vinyl amides such as N-vinylpyrrolidinone, N-vinylphthalimide, and N-vinylformamide with vinyltrisubstituted silanes catalyzed by [RuH(Cl)(CO)(PCy3)2] I is described. |
| Keywords: | Vinylsilanes Silylative coupling Ruthenium catalyst Silyl(vinyl)amides Vinylamides |
| 本文献已被 ScienceDirect 等数据库收录！ | |