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N-Heterocyclic carbene-palladium complex on polystyrene resin surface as polymer-supported catalyst and its application in Suzuki cross-coupling reaction |
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| Authors: | Jong-Ho Kim |
| Affiliation: | School of Chemical Engineering, Seoul National University, Seoul 151-744, South Korea |
| Abstract: | A poly(imidazoliummethyl styrene)-surface grafted-polystyrene resin was prepared by suspension polymerization. This was used as the polymer-supported carbene precursor for the palladium complex, which efficiently catalyzed the Suzuki cross-coupling of aryl halides and phenylboronic acid. |
| Keywords: | Polymer-supported N-heterocyclic carbene (NHC) Heterogeneous catalysis Palladium (Pd) Suzuki cross-coupling Imidazolium Suspension polymerization |
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