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Synthesis and simple separation of β-pyrrole sulfonated porphycenes
Authors:Tatsushi Baba
Institution:Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812-8581, Japan
Abstract:New water-soluble porphycenes having sulfonic acid groups at the β-pyrrolic positions were synthesized and characterized by UV-vis, NMR, IR, and mass spectroscopy as well as elemental analyses. The series of mono- to tri-sulfonato derivatives were simply separated by the extraction method.
Keywords:Water-soluble porphycene  Sulfonation of macrocycle  Separation with extraction
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