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A hetero Diels-Alder approach to the synthesis of the first angucyclinone and angucycline 5-aza-analogues |
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| Authors: | Sylvain C Collet,Claire Cariou,André Y Guingant,Nguyen Quang Vu |
| Affiliation: | a Laboratoire de Synthèse Organique, UMR CNRS 6513, FR CNRS 2465, Faculté des Sciences et des Techniques, UFR Sciences, 2 rue de la Houssinière, BP 92208 - 44322 Nantes Cedex 03, France b Laboratoire de Synthèse Organique, UMR CNRS 6011, Université du Maine, F-72085, Le Mans Cedex-9, France |
| Abstract: | The synthesis of two new heterodienes and their regioselective [4+2]cycloaddition reactions with several bromo-naphthoquinones allowed us to prepare the first angucyclinone and angucycline 5-aza-analogues. |
| Keywords: | Angucycline Angucyclinone Angucyclin(one) 5-aza-analogues Azadiene Bromo-naphthoquinone Hetero Diels-Alder reaction C-Glycoside |
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