An unusual twist conformation of 2-O-methyl-1,3,4,5-tetrakis-O-tert-butyldiphenylsilyl-myo-inositol |
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Authors: | Hidetoshi Yamada Kotaro Okajima Yusuke Nagata |
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Affiliation: | a School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan b Faculty of Pharmaceutical Sciences, Tokushima Bunri University, 180 Nishihamaboji, Tokushima 770-8514, Japan |
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Abstract: | ![]() The ring conformation of 2-O-methyl-1,3,4,5-tetrakis-O-tert-butyldiphenylsilyl-myo-inositol was in a twist form both in solid state and in solution. This is the first observation of a stable twist conformer induced by the introduction of bulky silyl protecting groups. |
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Keywords: | Ring conformation Twist form Bulky silyl protecting groups myo-inositol |
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