A new useful entry of IBX: the synthesis and structure of α-(2-iodobenzoyloxy)ketones |
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| Authors: | Zhen-liang Pan |
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| Affiliation: | State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China |
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| Abstract: | ![]()
α-Functionalized ketones can be conveniently prepared in one step by the reaction of ketones possessing α-methene with o-iodoxybenzoic acid (IBX) in the presence of potassium iodide. Methyl aryl ketones produced bi-substituted products, whereas the others gave mono-substituted ones. |
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| Keywords: | α-Functionalized ketones Hypervalent iodine IBX Structure Synthesis |
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