Structure and enantioselective synthesis of polyamine toxin MG30 from the venom of the spider Macrothele gigas |
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| Authors: | Nahoko Yamaji Manabu Horikawa Hideo Naoki Terumi Nakajima |
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| Institution: | a Suntory Institute for Bioorganic Research, Instrumental analysis, 1-1-1 Wakayamadai, Shimamoto-Cho, Mishima-Gun, Osaka 618-8503, Japan
b Institute of Ecology, Technical University Berlin, 10623 Berlin, Germany |
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| Abstract: | A novel polyamine toxin, named MG30, was isolated from the venom of the spider, Macrothele gigas, and its structure was elucidated by two-dimensional NMR and mass analysis. In addition, the enantioselective synthesis of MG30 was achieved to assign its absolute stereochemistry. |
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| Keywords: | Spider Polyamine toxin Macrothele gigas |
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