Photooxidation of aryl alkanes by a decatungstate/triethylsilane system in the presence of molecular oxygen |
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| Authors: | Ioannis N Lykakis |
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| Institution: | Department of Chemistry, University of Crete, 71409 Iraklion, Crete, Greece |
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| Abstract: | Decatungstate photocatalyzes the oxidation of aryl alkanes to the corresponding tertiary hydroperoxides and alcohols, in the presence of molecular oxygen. The addition of triethylsilane to the reaction mixture substantially increases the proportion of hydroperoxide formed. |
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| Keywords: | Photooxidation Aryl alkanes Hydroperoxides Decatungstate Polyoxometalate Triethylsilane |
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