Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: a general, regiospecific synthesis of α-aryl ketones |
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| Authors: | Michael W. Justik |
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| Affiliation: | Department of Chemistry, The University of Akron, Akron, OH 44325-3601, USA |
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| Abstract: | ![]()
The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs. |
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| Keywords: | Oxidative rearrangement Hypervalent iodine |
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