Homogeneous isotopic exchange between nickel(II) and bis(diethyldithiocarbamato)nickel(II) complex |
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| Authors: | T Gangaiah P Ramadevi G R K Naidu K Venugopal Chetty |
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| Institution: | (1) Chemistry Department, College of Engineering, Sri Venkateswara University, 517 502 Tirupati, (India);(2) Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085 Bombay, (India) |
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| Abstract: | Isotopic exchange behaviour of bis(diethyldithio carbamate) nickel(II) complex with nickel(II) in chloroform and methanol medium was studied. The studies were carried out at different temperatures varying the concentration of both metal ion and the complex. The results show that the complex is labile in the kinetic sense. Increase in temperature increases the isotopic exchange rate. The increase in concentration also results in enhancement of the rate of reaction. |
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