Liquid crystalline complexes of 4-alkoxystilbazoles with silver 1,12-dodecylene disulphate |
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Authors: | H Loc Nguyen Peter Horton Michael Hursthouse Duncan Bruce |
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Abstract: | A new series of metal complexes of silver(I) 1,12-dodecylene disulphate with 4-alkoxystilbazole ligands has been synthesized. These difunctional silver stilbazole complexes are mesomorphic, showing a nematic phase at short chain lengths and SmA and SmC phases at longer chain lengths. The single crystal X-ray structure of the hexyloxy homologue shows a polymerized arrangement of sulphate-bridged dimers. |
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