Synthetic studies toward the bryostatins: a substrate-controlled approach to the A-ring |
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| Authors: | Keck Gary E Welch Dennie S Vivian Paige K |
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| Affiliation: | Department of Chemistry, University of Utah, 315 South 1400 East RM 2020, Salt Lake City, Utah 84112-0850, USA. keck@chemistry.utah.edu |
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| Abstract: | [reaction: see text] The synthesis of a C1-C13 A-ring subunit of bryostatin 1 is detailed. The key features of the approach include the convergent fragment assembly with a highly stereoselective construction of the C7-C8 bond indicated above. |
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