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(2,2′‐Bi­pyridine‐κ2N,N′)(dichromato‐κO)copper(II)
Authors:Paul A Maggard  Amy L Kopf  Charlotte L Stern  Kenneth R Poeppelmeier
Abstract:The title compound, Cu(Cr2O7)(C10H8N2)2], a new mixed‐metal molecular compound, contains isolated molecular units, each comprised of one CuII atom coordinated to two 2,2′‐bi­pyridine ligands and also to an oxy­gen vertex of a dichromate anion. The CuII atom has an approximate trigonal–bipyramidal geometry, which is consistent with previous studies. Both enantiomers of the chiral complex mol­ecule are present and are related by inversion centers. In a reported pyridine analogue, achiral Cu(Cr2O7)(pyridine)4] chains pack in the non‐centrosymmetric space group Pna21. Differences in the organic ligands influence the chirality and dimensionality of the Cu—Cr2O7 bonding.
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