catena‐Poly[[bis(nicotinamide‐κN1)copper(I)]‐μ‐thiocyanato‐κ2N:S] |
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Authors: | Christian Nther Inke Jeß |
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Institution: | Christian Näther,Inke Jeß |
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Abstract: | The CuI cations in the title compound, Cu(NCS)(C6H6N2O)2]n, are coordinated by N atoms from each of two mirror‐related nicotinamide ligands, as well as by one N atom of one thiocyanate ligand and one S atom of a symmetry‐related thiocyanate ligand, within a slightly distorted tetrahedron. The CuI cations and the thiocyanate anions are located on a crystallographic mirror plane and the nicotinamide ligands occupy general positions. The CuI cations are connected by the thiocyanate anions to form chains in the direction of the crystallographic a axis. These chains are connected by hydrogen bonds between the amide H atoms and the O atoms of adjacent nicotinamide ligands, to give a three‐dimensional structure. |
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