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Bis[1‐(pyridin‐2‐yl)­ethano­ne‐κN 4‐phenyl­thio­semicarbazonato‐κ2N4,S]­manganese(II)
Authors:Anwar Usman  Ibrahim Abdul Razak  Suchada Chantrapromma  Hoong‐Kun Fun  A Sreekanth  S Sivakumar  M R Prathapachandra Kurup
Abstract:One half of the mol­ecule of the title complex, Mn(C14H13N4S)2], is related to the other half by a twofold axis passing through the Mn atom. This high‐spin Mn atom is six‐coordinated, in an octahedral geometry, by the azomethine N, the pyridyl N and the thiol­ate S atom of two planar 1‐­(pyridin‐2‐yl)­ethanone N(4)‐phenyl­thio­semicarbazone lig­ands. In the crystal, the mol­ecules are interconnected by N—­H?S and C—H?N interactions, forming a three‐dimensional network.
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