| 新的双胺双膦钌配合物的合成、表征和催化性能 |
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| 引用本文： | 许翩翩,高景星,王文国,陈忠,黄培强,万惠霖,蔡启瑞.新的双胺双膦钌配合物的合成、表征和催化性能[J].物理化学学报,1997,13(6):484-488. |
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| 作者姓名： | 许翩翩 高景星 王文国 陈忠 黄培强 万惠霖 蔡启瑞 |
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| 作者单位： | Department of Chemistry,State Key Laboratory of Physical Chemistry of Solid Surface and Institute of Physical Chemistry,Xiamen University,Xiamen 361005 |
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| 摘 要： |
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| 关 键 词： | 双胺双膦钌配合物 苯乙酮 氢化 |
| 收稿时间： | 1997-02-13 |
| 修稿时间： | 1997-04-09 |
Synthesis, Characterization and Catalytic Properties of New Diamino/Diphosphine Ruthenium Complexes |
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| Xu Pian-Pian,Gao Jing-Xing,Wang Wen-Guo,Chen Zhong,Huang Pei-Qiang,Wan Hui-Qiang,Cai Qi-Rui.Synthesis, Characterization and Catalytic Properties of New Diamino/Diphosphine Ruthenium Complexes[J].Acta Physico-Chimica Sinica,1997,13(6):484-488. |
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| Authors: | Xu Pian-Pian Gao Jing-Xing Wang Wen-Guo Chen Zhong Huang Pei-Qiang Wan Hui-Qiang Cai Qi-Rui |
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| Institution: | Department of Chemistry,State Key Laboratory of Physical Chemistry of Solid Surface and Institute of Physical Chemistry,Xiamen University,Xiamen 361005 |
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| Abstract: | Polydentate ligands, N,N'-biso-(diphenylphosphino)benzylidene]-1,2-propane-diamine P2N2Me for short] and N,N'-biso-(diphenylphosphino)benzy1]-1,2-propanediamine P2N2 H4Me for short] have been synthesized. The interaction of RuCl2(DMSO)4 with one equivalent of P2N2Me or P2N2H4Me in refluxing toluene gave trans-RuCl2(P2N2Me) and trans-RuCl2(P2N4H4Me) in good yield, respectively. The ligands and the complexes have been fully characterized by elemental analysis and spectroscopic methods. The complexes act as an excellent catalyst precursor in hydrogen transfer hydrogenation of acetophenone in catalyst: acetophenone :iso-PrOK of 1: 100: 15, leading to 2-phenylethanol of 89-96% yield. |
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| Keywords: | Aminophosphine ruthenium complex Acetophenone Hydrogenation |
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