| CF2自由基A态伸缩振动频率的测定 |
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| 引用本文： | 王储记,肖迎胜,冉琴,楮艺伟,陈从香,俞书勤,马兴孝.CF2自由基A态伸缩振动频率的测定[J].物理化学学报,1997,13(4):297-300. |
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| 作者姓名： | 王储记 肖迎胜 冉琴 楮艺伟 陈从香 俞书勤 马兴孝 |
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| 作者单位： | Department of Chemical Physics,University of Science and Technology of China,Hefei 230026 |
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| 摘 要： |
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| 关 键 词： | CF2自由基 伸缩振动频率 |
| 收稿时间： | 1996-12-03 |
| 修稿时间： | 1997-01-28 |
Determination of A-State Streching Frequencies of CF2 Radical |
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| Wang Chu-Ji,Xiao Ying-Sheng,Ran Qin,Chu Yi-Wei,Chen Cong-Xiang,Yu Shu-Qin,Ma Xing-Xiao.Determination of A-State Streching Frequencies of CF2 Radical[J].Acta Physico-Chimica Sinica,1997,13(4):297-300. |
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| Authors: | Wang Chu-Ji Xiao Ying-Sheng Ran Qin Chu Yi-Wei Chen Cong-Xiang Yu Shu-Qin Ma Xing-Xiao |
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| Institution: | Department of Chemical Physics,University of Science and Technology of China,Hefei 230026 |
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| Abstract: | Laser induced fluorescence excitation spectroscopy has been used to determine the previously ambiguous assignments of A-state stretching frequencies of CF2 radical under supersonic free jet conditions. The measured frequencies are v’1=1012.1±0.5cm-1, v’3=1180.2±0.5cm-1, which is in good agreement with Cameron's6] calculation result. Furthermore, some transitions attributed to the (1,n-2,0)←(0,0,0), n≦6 progressions are first reported, and new parameters are derived from the spectra obtained. |
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| Keywords: | 2 radical' ') CF2 radical" target="_blank">">CF2 radical Stretching frequencies |
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