Synthesis and structure of a product of interaction of acetonitrile with hydrogen bromide, [H2N=C(Me)−NH−C(Me)Br2]Br |
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Authors: | I. V. Oshanina N. A. Kokoreva L. G. Bruk O. N. Temkin I. L. Eremenko S. E. Nefedov |
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Affiliation: | (1) Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571 Moscow;(2) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907 Moscow |
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Abstract: | A mixture of solid products was obtained upon absorption of dry HBr by MeCN. One of the products, [H2N=C(Me)−NH−C(Me)Br2]Br, was isolated as white single crystals and characterized by X-ray diffraction analysis. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2274–2277, November, 1998. |
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Keywords: | acetonitrile hydrogen bromide X-ray diffraction analysis |
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