Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane |
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| Authors: | Bae Youn-Sang Farha Omar K Spokoyny Alexander M Mirkin Chad A Hupp Joseph T Snurr Randall Q |
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| Institution: | Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. snurr@northwestern.edu. |
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| Abstract: | Separation of CO(2)/CH(4) mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO(2) over CH(4) ( approximately 17) are obtained, especially in the material with open metal sites. |
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