Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions: A simple synthesis of Dibenzo |
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| Authors: | Reisch Bratcher Scott |
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| Institution: | Department of Chemistry, Merkert Chemistry Center Boston College, Chestnut Hill, Massachusetts 02467-3860, USA. |
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| Abstract: | Palladium catalysis has been found to offer an effective solution-phase alternative to gas-phase flash vacuum pyrolysis as a method for converting the planar ring system of 7, 10-di(2-bromophenyl)fluoranthene (4) to that of the C(28)H(14) bowl-shaped fullerene fragment dibenzoa,g]corannulene (5). |
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