Synthesis of the tricyclic core of aldingenin B by oxidative cyclo-ketalization of an alkyne-diol |
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| Authors: | Yang Jingyue Tummatorn Jumreang Slegeris Rimantas Tlais Sami F Dudley Gregory B |
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| Institution: | Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, USA. |
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| Abstract: | The preparation and selenium-mediated cyclo-ketalization of an alkyne-diol is described as a model study for the synthesis of aldingenin B. The oxidative cyclization is a simplifying transformation for aldingenin B, as it provides a convenient method for generating the tricylic core of the natural product from a functionalized cyclohexane. |
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