Palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates |
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Authors: | Chen Ru Liu Saiwen Liu Xinhua Yang Luo Deng Guo-Jun |
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Institution: | Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China. |
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Abstract: | A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate to good yields. |
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