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Palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates
Authors:Chen Ru  Liu Saiwen  Liu Xinhua  Yang Luo  Deng Guo-Jun
Institution:Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China.
Abstract:A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate to good yields.
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