| Solvothermal Synthesis and Crystal Structure of [H2N（CH2）2NH3]{Co[H2N（CH2）2NH2]3}[SbSe4] |
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| 引用本文： | 付明来,陈文通,蔡丽珍,刘冰,郭国聪,黄锦顺.Solvothermal Synthesis and Crystal Structure of [H2N（CH2）2NH3]{Co[H2N（CH2）2NH2]3}[SbSe4][J].结构化学,2004,23(7):731-734. |
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| 作者姓名： | 付明来 陈文通 蔡丽珍 刘冰 郭国聪 黄锦顺 |
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| 作者单位： | FU Ming-Lai a，b CHEN Wen-Tong a CAI Li-Zhen a LIU Bing a GUO Guo-Cong a② HUANG Jin-Shun a② a (State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) b (Graduate School of the Chinese Academy of Sciences，Beijing 100039，China) |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China (No. 20001007，20131020)，Natural Science Foundation of the Chinese Academy of Sciences (KJCX2-H3) and Natural Science Foundation of Fujian Province (No. 2000F006，2003I031) |
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| 摘 要： | 1 INTRODUCTION The chalcogenidometallates with open frame- works have attracted considerable interest as pos- sible zeolite-like materials, of which highly interes- ting properties could be expected. Over the last de- cades a large number of thioanti…
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| 关 键 词： | 合成 晶体结构 钴配合物 溶剂热法 硒基锑酸盐 |
Solvothermal Synthesis and Crystal Structure of [H2N(CH2)2NH3]{Co[H2N(CH2)2NH2]3}[SbSe4] |
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| Institution: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;Graduate School of the Chinese Academy of Sciences,Beijing 100039,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| Abstract: | The new molecular metal chalcogenoantimonate, 2-aminoethylammonium tris(1, 2-ethylenediamine)cobalt tetraselenoantimonate, enH]Co(en)3]SbSe4] (en = ethylenediamine), has been synthesized by solvothermal reaction in an ethylenediamine/methanol solution at 443 K and structurally characterized by X-ray crystallography. The crystal belongs to triclinic, space group P1 with a = 8.900(4), b = 9.663(5), c = 14.361(6) ? = 104.783(18), = 92.4220(10), = 109.9920(10), C8H33CoN8SbSe4, Mr = 737.94, V = 1110.7(10) ?, Z = 2, Dc = 2.207 g/cm3, F(000) = 702, = 8.525 mm-1, R = 0.0648, wR = 0.0755 and S = 1.005. The structure contains tetrahedral SbSe4]3- anion and octahedral Co(en)3]2+ cation, as well as the monoprotonated ethylenediamine cation enH]+. |
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| Keywords: | solvothermal selenoantimonate crystal structure cobalt |
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