Specific MARY spectrum from radical anion of pentafluorobenzene |
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| Authors: | E V Kalneus A A Kipriyanov P A Purtov D V Stass Yu N Molin |
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| Institution: | 1. Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Institutskaya ulitsa 3, 630090, Novosibirsk, Russian Federation
2. Novosibirsk State University, Novosibirsk, Russian Federation
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| Abstract: | The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system. |
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