| 表面活性剂模板在空气-水界面ZrO2薄膜中的稳定性 |
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| 引用本文： | 刘孝恒,JohnWhite,汪信.表面活性剂模板在空气-水界面ZrO2薄膜中的稳定性[J].无机化学学报,2005,21(12):1827-1830. |
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| 作者姓名： | 刘孝恒 JohnWhite 汪信 |
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| 作者单位： | 1. 南京理工大学材料化学实验室,南京,210094
2. 澳大利亚国立大学化学院,堪培拉,0200 |
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| 基金项目： | 国家自然科学基金(No.50372028)资助项目。 |
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| 摘 要： | 采用模板——十二烷基苯磺酸(DBS-H)在空气-水界面组装ZrO2薄膜，研究了DBS-H在ZrO2自组装薄膜中的水溶性、化学稳定性、热稳定性和光化学稳定性。模板的各类稳定性将直接控制ZrO2薄膜结构，主要表现在层间距变化上。从模板与Na2SiO3反应的研究中获得了一种制备ZrO2 / SiO2复合氧化物薄膜的新方法，并推测出该复合薄膜的结构。
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| 关 键 词： | ZrO2薄膜 十二烷基苯磺酸(DBS-H) 层间距 ZrO2 / SiO2薄膜 |
| 文章编号： | 1001-4861(2005)12-1827-04 |
| 收稿时间： | 2005-06-20 |
| 修稿时间： | 2005-07-26 |
Stabilities of Dodecylbenzenesulfonic Acid as Template of ZrO2 Films at Air-water Interface |
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| LIU Xiao-Heng,John White and WANG Xin.Stabilities of Dodecylbenzenesulfonic Acid as Template of ZrO2 Films at Air-water Interface[J].Chinese Journal of Inorganic Chemistry,2005,21(12):1827-1830. |
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| Authors: | LIU Xiao-Heng John White and WANG Xin |
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| Institution: | Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094,Research School of Chemistry, Australian National University, Canberra 0200 and Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094 |
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| Abstract: | An anionic surfactant, 4-dodecylbenzenesulfonic acid (DBS-H), has been used to prepare ZrO2 films as the template at the air-water interface. Further investigations have been focused on DBS-H template stabilities, which control the structure as well as properties of the products. Significantly, a novel composite ZrO2 / SiO2 film could be obtained by reacting ZrO2 / DBS-H composite with Na2SiO3. |
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| Keywords: | ZrO2 film dodecylbenzenesulfonic acid(DBS-H) d-spacing ZrO2 / SiO2 film |
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