| Synthesis, Crystal Structure and Electrochemical Property of 5,10,15,20-Tetrakis（4-chlorophenyl）porphyrin |
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| 作者姓名： | ZHU Min LU Gui-Fen ZHU Yu LV Ai-Xiang OU Zhong-Ping |
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| 作者单位： | School of Chemistry ＆ Chemical Engineering, Jiangsu University, Zhenjiang 212013, China |
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| 基金项目： | The project was supported by the National Natural Science Foundation of China，the Jiangsu Higher Education Institutions，Jiangsu Planned Projects for Postdoctoral Research Funds (1102126C). Foundation of UJS (No. 09JDG055) is gratefully acknowledged |
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| 摘 要： | The title compound 5,10,15,20-tetrakis(4-chlorophenyl)porphyrin was synthesized and structurally characterized by X-ray single-crystal diffraction method. Crystal data: triclinic, space group P, Z=1, C50H32Cl4N4, Mr=830.60, a=6.4316(13), b=11.322(2), c=13.833(3) , α =91.44(3), β=91.06(2), γ=92.67(3)°, V=1005.7(3)3 , Dc=1.371 g/cm3 , μ(MoKα)=0.34 mm-1 , F(000)=428, R=0.0563 and wR=0.0867 for 2712 observed reflections with I > 2σ(I). X-ray analysis reveals the phenyl rings and the pyrrole rings are not in the same plane. The dihedral angles between adjacent phenyl rings and pyrrole rings are 66.1 and 66.8°, respectively.
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| 关 键 词： | porphyrin crystal structure electrochemical property |
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