Palladium-catalyzed addition of nitrogen pronucleophiles to alkylidenecyclopropanes |
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| Authors: | Siriwardana Amal I Kamada Michiru Nakamura Itaru Yamamoto Yoshinori |
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| Institution: | Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan. |
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| Abstract: | The inter- and intramolecular additions of cyclic amides (nitrogen pronucleophiles) to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh(3))(4), affording the corresponding hydroamination products in good to high yields with high regioselectivities. The ring opening of methylenecyclopropanes occurred at the distal position of the cyclopropane ring. |
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