Structure of [RuNO(NH3)3(H2O)Cl](NO3)2, product of interaction between hydroxonitrotriamminenitrosoruthenium(II) chloride and nitric acid |
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| Authors: | V. A. Emel’yanov E. V. Kabin I. A. Baidina |
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| Affiliation: | (1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia;(2) Novosibirsk State University, Novosibirsk, Russia |
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| Abstract: | The structure of the product formed on boiling [RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O in 3 M HNO3 is determined by XRD. The crystals belong to monoclinic symmetry. Crystallographic data for H11ClN6O8Ru are: a = 13.7924(4) ?, b = 6.9114(2) ?, c = 12.3577(4) ?, β = 111.863(1)°, V = 1093.27(6) ?3, Z = 4, d calc = 2.185 g/cm3, space group Cc. The structure is built of complex [RuNO(NH3)3(H2O)Cl]2+ cations and NO3− anions. The compound is studied by IR spectroscopy and X-ray phase analysis. Original Russian Text Copyright ? 2009 by V. A. Emel’yanov, E. V. Kabin, and I. A. Baidina __________ Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 598–601, May–June, 2009. |
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| Keywords: | ruthenium nitroso complexes ammine complexes X-ray diffraction analysis crystal chemistry |
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