Parallel synthesis of terminal alkynes using a ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate |
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| Authors: | Barrett Anthony G M Hopkins Brian T Love Andrew C Tedeschi Livio |
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| Affiliation: | Department of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ, England. agmb@imperial.ac.uk |
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| Abstract: | ![]()
ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate has been prepared, and the supported reagent has been effectively employed in the conversion of a variety of aldehydes into terminal alkynes under mild reaction conditions. The influence of cross-link structure, comonomers, and polymer structure on reaction efficiency has been examined. [structure: see text] |
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