Expanding stereochemical and skeletal diversity using petasis reactions and 1,3-dipolar cycloadditions |
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| Authors: | Muncipinto Giovanni Kaya Taner Wilson J Anthony Kumagai Naoya Clemons Paul A Schreiber Stuart L |
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| Affiliation: | Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States. |
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| Abstract: | ![]()
A short and modular synthetic pathway using intramolecular 1,3-dipolar cycloaddition reactions and yielding functionalized isoxazoles, isoxazolines, and isoxazolidines is described. The change in shape of previous compounds and those in this study is quantified and compared using principal moment-of-inertia shape analysis. |
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