蓝色氧化钨的光电子能谱研究

本文用光电子能潜技术对蓝色氧化钨的表面价态进行了一系列研究。结果表明:蓝色氧化钨并不是单一价态的氧化钨,而是由W⁺⁵和W⁺⁶两种价态组成。氩离子刻蚀,真空高温处理都是一个失氧还原过程,也是钨由高价态向低价态的转变过程。同时,费密能级附近的态密度随着价态变低而逐渐增加。关键词：

PHOTOEMISSION STUDIES ON THE BLUE TUNGSTEN OXIDES

A series of studies were conducted for surface valency in blue tungsten oxides by using pho-toemission technique. Rusults show that, the blue tungsten oxide contains not only one kind of valency, but conbination of two valences, namely the conbination of W⁺⁵ and W⁺⁶, and also the process of argon ion eching and high temperature treatment all induce the loss of oxygen in W-chemical reduction process, which causes W transfer from high valence to low valence. Meanwhile, the density of state near Fermi level increases with the change from high valence to low valence.