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| 配合物[Cu2(phen)2](SiW12O40)(H2O)7的合成、晶体结构及电化学分析 | |
| 引用本文： | 李昶红,何晓梅,李薇,徐伟箭,杨颖群. 配合物[Cu2(phen)2](SiW12O40)(H2O)7的合成、晶体结构及电化学分析[J]. 无机化学学报, 2006, 22(6): 1072-1076 |
| 作者姓名： | 李昶红 何晓梅 李薇 徐伟箭 杨颖群 |
| 作者单位： | 1. 湖南大学化学化工学院,长沙,410082;湖南工学院化学化工系,衡阳,421008 2. 湖南工学院化学化工系,衡阳,421008 3. 衡阳师范学院化学与材料科学系,衡阳,421008 4. 湖南大学化学化工学院,长沙,410082 |
| 基金项目： | 教育部高校骨干教师资助计划;湖南省教育厅科研项目;衡阳师范学院校科研和教改项目 |
| 摘 要： | The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline (phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P1 with a=1.158 46(15) nm, b=1.658 8(2) nm, c=1.664 4(2) nm, α=82.090(2)°, β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7) nm3, Dc=3.887 g·cm-3, Z=2, F(000)=3 196. R1=0.086 7, wR2=0.185 8. The structure shows that the copper(Ⅱ) atom is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC: 298807. |
| 关 键 词： | 铜(Ⅱ)配合物； 钨硅酸； 晶体结构； 电化学性质 |
| 文章编号： | 1001-4861(2006)06-1072-05 |
| 收稿时间： | 2005-09-15 |
| 修稿时间： | 2006-04-10 |
Synthesis, Crystal Structure and Electrochemical Properties of Complex [Cu2(phen)2](SiW12O40)(H2O)7 |
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| LI Chang-Hong,HE Xiao-Mei,LI Wei,XU Wei-Jian and YANG Ying-Qun. Synthesis, Crystal Structure and Electrochemical Properties of Complex [Cu2(phen)2](SiW12O40)(H2O)7[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(6): 1072-1076 | |
| Authors: | LI Chang-Hong HE Xiao-Mei LI Wei XU Wei-Jian YANG Ying-Qun |
| Affiliation: | College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421008,College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 and Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421008 |
| Abstract: | The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline(phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P-1 with a=1.15846(15) nm, b=1.658 8(2) nm, c=1.6644(2) nm, α=82.090(2)°,β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7)is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC:298807. |
| Keywords: | silicotungstic acid crystal structure electrochemical property |
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