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Palladium Catalyzed Suzuki Cross-coupling Reaction in Molten Tetra-n-butylammonium Bromide
引用本文:邹岳 王全瑞 陶凤岗 丁宗彪. Palladium Catalyzed Suzuki Cross-coupling Reaction in Molten Tetra-n-butylammonium Bromide[J]. 中国化学, 2004, 22(2): 215-218. DOI: 10.1002/cjoc.20040220223
作者姓名:邹岳 王全瑞 陶凤岗 丁宗彪
作者单位:DepartmentofChemistry,FudanUniversity,Shanghai200433,China
摘    要:A practical procedure for palladium catalyzed Suzuki cross-coupling reaction of arylboronic acids with aryl halides, including aryl chlorides in molten tetra-n-butylammonium bromide (TBAB) was developed. The reaction exhibits high efficiency and functional group tolerance. The recovery of the catalyst and molten n-Bu4NBr was also investigated.

关 键 词:钯 联芳基 四氮溴化丁基铵 铃木耦合

Palladium Catalyzed Suzuki Cross-coupling Reaction in Molten Tetra-n-butylammonium Bromide
ZOU,Yue WANG,Quan-Rui TAO,Feng-Gang DING,Zong-Biao. Palladium Catalyzed Suzuki Cross-coupling Reaction in Molten Tetra-n-butylammonium Bromide[J]. Chinese Journal of Chemistry, 2004, 22(2): 215-218. DOI: 10.1002/cjoc.20040220223
Authors:ZOU  Yue WANG  Quan-Rui TAO  Feng-Gang DING  Zong-Biao
Affiliation:ZOU,Yue WANG,Quan-Rui* TAO,Feng-Gang DING,Zong-Biao Department of Chemistry,Fudan University,Shanghai 200433,China
Abstract:A practical procedure for palladium catalyzed Suzuki cross-coupling reaction of arylboronic acids with aryl hal-ides, including aryl chlorides in molten tetra-n-butylammonium bromide (TBAB) was developed. The reaction exhibits high efficiency and functional group tolerance. The recovery of the catalyst and molten n-Bu4NBr was also investigated.
Keywords:palladium   tetra-n-butylammonium bromide   arylboronic acids   Suzuki coupling   biaryl  
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