| Synthesis and Crystal Structure of a Molybdenum Carbonyl Compound with Thiolate and Dithiocarbamate Ligands, [Bu4N][（OC）4Mo（μ-SC6H5）2Mo（C5H10CNS2）（CO）2] |
| |
| 引用本文： | 庄伯涛,潘国华,周张锋,何玲洁,吴克琛.Synthesis and Crystal Structure of a Molybdenum Carbonyl Compound with Thiolate and Dithiocarbamate Ligands, [Bu4N][（OC）4Mo（μ-SC6H5）2Mo（C5H10CNS2）（CO）2][J].结构化学,2006,25(1):63-67. |
| |
| 作者姓名： | 庄伯涛 潘国华 周张锋 何玲洁 吴克琛 |
| |
| 作者单位： | State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China |
| |
| 基金项目： | FinancialsupportswereTheNationalNatureScienceFoundationofChina(No.90203017)andTheNationalBasicResearchProgram(No.2004CB720605). |
| |
| 摘 要： | 1INTRODUCTION The chemistry of molybdenum-sulfur compounds has attracted the attention from chemists,bioinor-ganic chemists and biochemists because Mo and S are important elements of metal enzymes especially N2-ase1~6].Since the di-molybdenum(0)thiolate com-pound with aMo2S2]2?unit core and two-electron transfer character,Et4N]2Mo2(SR)2(CO)8](R=Ph,tBu),was synthesized by introducing thiolate ligands into Mo(CO)67],the chemistry of complexes conta-ining low valence molybdenum at…
|
| 关 键 词： | [Bu4N][（OC）4Mo（μ-SC6H5）2Mo（C5H10CNS2）（CO）2] 合成 晶体结构 钼碳酰基配合物 硫醇盐 二硫代氨基甲酸酯配合基 |
| 本文献已被 CNKI 维普 等数据库收录！ |
