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Synthesis and electrochemical reaction with lithium of mesoporous iron oxalate nanoribbons
Authors:Aragón María José  León Bernardo  Pérez Vicente Carlos  Tirado José L
Affiliation:Laboratorio de Química Inorgánica, Universidad de Córdoba, Edificio C3, Campus de Rabanales, 14071 Córdoba, Spain.
Abstract:Mesoporous FeC 2O 4 was prepared by dehydration of bulk monoclinic- and micellar orthorhombic FeC 2O 4.2H 2O precursors at 200 degrees C. The micellar material shows nanoribbon shaped particles, which are preserved after dehydration. These solids are used as high-capacity lithium storage materials with improved rate performance. The mesoporous nanoribbons exhibit higher capacities close to 700 mA h/g after 50 cycles at 2C (C = 1 Li h (-1) mol (-1)) rate between 0 and 2 V.
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