Thermodynamic parameters of excess and absolute adsorption of CH4 and SF6 on carbons |
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Authors: | Pribylov A A Kalinnikova I A Shekhovtsova L G Kalashnikov S M |
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Institution: | (1) Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915 Moscow, Russian Federation |
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Abstract: | Isosteres, isosteric heats, and heat capacities of methane and sulfur hexafluoride on carbons with different porosities were calculated to characterize the excess adsorption and absolute adsorption. The nonlinear character of isosteres of excess adsorption and absolute adsorption of sulfur hexafluoride on FAS carbon with developed mesoporosity was shown. |
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Keywords: | adsorption isostere adsorption heat partial thermal capacity of adsorbate |
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