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明胶基多孔碳球电极材料的制备及电化学性能研究
引用本文:慈颖,葛军,王小峰,陈文浩,郭燕川,陈丽娟.明胶基多孔碳球电极材料的制备及电化学性能研究[J].无机化学学报,2007,23(2):365-368.
作者姓名:慈颖  葛军  王小峰  陈文浩  郭燕川  陈丽娟
作者单位:1. 中国科学院理化技术研究所,北京,100080;中国科学院研究生院,北京,100049
2. 中国科学院理化技术研究所,北京,100080
摘    要:Gelatin-based porous carbon beads have been fabricated from gelatin micro-spheres by means of solidification, carbonization and chemical activation with KOH. The physical properties of gelatin-based porous carbon beads were studied by a t-plot method based on N2 adsorption isotherms. The gelatin-based porous carbon beads activated at 800 ℃ exhibited the largest specific surface area and resulted in the highest capacitance. Carbon/carbon super-capacitors cells assembled with the electrode materials in 1.0 mol·L-1 NEt4BF4 / acetonitrile electrolyte have also been studied. The electrochemical properties of gelatin-based porous carbon beads electrode were studied by using constant-current discharge tests. The results indicate that the gelatin-based porous carbon beads electrode is with good cycling stability and specific capacitance of 119.8 F·g-1.

关 键 词:明胶基多孔碳球    活化温度    超级电容器    性能
文章编号:1001-4861(2007)02-0365-04
修稿时间:2006-10-16

Gelatin-based Porous Carbon Beads: Preparation and Application as Electrodes in Super-capacitors
CI Ying,GE Jun,WANG Xiao-Feng,CHEN Wen-Hao,GUO Yan-Chuan and CHEN Li-Juan.Gelatin-based Porous Carbon Beads: Preparation and Application as Electrodes in Super-capacitors[J].Chinese Journal of Inorganic Chemistry,2007,23(2):365-368.
Authors:CI Ying  GE Jun  WANG Xiao-Feng  CHEN Wen-Hao  GUO Yan-Chuan and CHEN Li-Juan
Institution:Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080;Graduate University of Chinese Academy of Sciences, Beijing 100049,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080;Graduate University of Chinese Academy of Sciences, Beijing 100049,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080,Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080 and Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080
Abstract:
Keywords:gelatin-based carbon beads  activation temperature  super-capacitor  properties
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