N-aminoazetidinecarboxylic acid: direct access to a small-ring hydrazino acid |
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| Authors: | Declerck Valérie Aitken David J |
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| Institution: | Laboratoire de Synthe?se Organique et Me?thodologie, ICMMO (UMR 8182-CNRS), Universite? Paris-Sud 11, 15 rue Georges Clemenceau, 91405 Orsay cedex, France. |
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| Abstract: | A short and efficient synthesis of the previously unknown N-aminoazetidinecarboxylic acid has been established using a photochemical 2 + 2] cycloaddition strategy starting from 6-azauracil. Chiral derivatization with a nonracemic oxazolidinone provided access to both enantiomers of the title product. |
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